Friday, December 7, 2018
gasoline octane booster mmt dosage list and relevant Mn contents
Tuesday, December 4, 2018
Methyl cyclopentadiene manganese Tricarbonyl MSDS
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MATERIAL SAFETY
DATA SHEET
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Chemical Chinese
name
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甲基环戊二烯三羰基锰
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Chemical Alias
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Unleaded gasoline antiknock
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Chemical name
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Methylcyclopentadienyl Manganese Tricarbonyl
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Abbreviation
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MMT
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EINECS number
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235-166-5
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CAS No.
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12108-13-3
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Manufacture
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SNF PETROCHEM CO.,LTD.
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Emergency telephone
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0086-18945064260
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Part Two Hazards identification
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Label
elements of the substance according to GHS(the fourth revised edition):
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Pictogram
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Signal
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Danger
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Hazard statement(s)
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H300 Fatal if swallowed
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H330 Fatal if inhaled
Toxic in
contact with skin.
Suspected of
causing cancer.
Toxic to
aquatic life
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Precautionary statements
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P260 Do not breathe dust/fume/gas/mist/vapours/spray.
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P264 Wash thoroughly after handling.
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P270 Do not eat, drink or smoke when using
this product.
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P271 Use only outdoors or in a
well-ventilated area.
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P280 Wear protective gloves/eye
protection/face protection.
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P301 + P310 IF SWALLOWED: Immediately call
a POISON CENTER/doctor.
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P304 + P340 IF INHALED: Remove person to
fresh air and keep comfortable for breathing.
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P405 Store locked up.
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P403+P233 Store in a well-ventilated place.
Keep container tightly closed.
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P501 Dispose of contents/container in
accordance with local/regional/national/ international regulations.
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Ingredient
name
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Content
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CAS No.
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Methylcyclopentadienyl
manganese tricarbonyl
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60%
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12108-13-3
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alkane
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39.5%
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109-66-0
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Olefins
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0.5%
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504-60-9
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Skin contact
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Flush contaminated skin with plenty
of water. Continue to rinse for at least 10 minutes. Remove
contaminated clothing and shoes. Wash contaminated
clothing thoroughly with water before removing
or wear gloves. Wash clothing before
reuse. Clean shoes thoroughly before reuse. Get medical attention
immediately.
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Eye contact
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Immediately flush eyes with plenty of
water for at least 15 minutes, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention
immediately.
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Inhalation
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Move exposed to fresh air. If it is
suspected that fumes are still present, the rescuer should wear an
appropriate mask or self-contained breathing apparatus. Keep person warm and
at rest. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may
be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. If unconscious, place in recovery position and get medical
attention immediately. Maintain an open airway. Loosen tight clothing such as
a collar, tie, belt or waistband.Get medical attention immediately.
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Ingestion
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Remove dentures if any. Move exposed
person to fresh air. Keep person warm and at rest. If material has
been swallowed and the exposed person
is conscious, give small quantities of water to drink. Stop if the exposed
person feels sick as vomiting may be dangerous. Aspiration hazard if
swallowed. Can enter lungs and cause damage. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should
be kept low so that vomit does not enter the lungs. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.Get medical attention
immediately.
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Special exposure hazards
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Flammable liquid and vapour. Vapour
may cause flash fire. Vapours may accumulate in low or confined areas or
travel a considerable distance to a source of ignition and flash back. Runoff
to sewer may create fire or explosion hazard. This material is very toxic to
aquatic organisms. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or
drain.
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Harmful combustion products
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Some Irritating and corrosive toxic gas were
possibly produced.
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Extinguishing media Suitable
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Use dry chemical, CO2, water spray
(fog) or foam.Do not use water jet.
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1.Personal precautions : Immediately contact emergency personnel.
Eliminate all ignition sources. Keep unnecessary personnel away. Use suitable
protective equipment. Do not touch or walk through spill material.
2.Environmental precautions : Avoid dispersal of spill material and
runoff and contact with soil, waterways, drains and sewers.
3.Treatment method: Rapidly evacuate workers from the contaminated area
to the safe place. It is recommended that emergency personnel wear goggles
and self-contained positive pressure respirators, protective clothing. Use vacuum sucking device or clean up the
material and then place it in the appropriate special container, the overflow material should be immediately
cleaned. During cleaning, use appropriate
protective facilities, and keep ventilation.
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Part Seven Handling and storage
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Handling
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Avoid contact with
eyes, skin and clothing. Keep container closed. Use only with adequate
ventilation. Do not breathe vapour or mist. Keep away from heat, sparks and
flame. To avoid fire or explosion, dissipate static electricity during
transfer by earthing and bonding containers and equipment before transferring
material. Use explosion-proof electrical (ventilating, lighting and material
handling) equipment. Wash thoroughly after handling.
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Storage
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Keep the product away from other products. The
container should be stored in a cool,
well-ventilated area. Keep container closed before use.
Avoid all possible sources of
ignition ( a spark or a flame ). Use the
explosion-proof lighting, ventilation facilities.
Forbidden to use the mechanical equipment and tools
that are liable to produce the
spark. Storage
areas should be equipped with emergency treatment equipment for
leakage and suitable collecting materials.keep in a dark place.
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Part
Eight Exposure controls/personnel protection
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Monitoring
method
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Engineering control
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Handling
can be carried out in a closed area against light with a good natural
ventilation
Limited MMT TWA：0.2mg/m3 STEL：0.6mg/m3
Aromatics . TWA：100ppm STEL：125ppm
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Respiratory protection
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Gas
masks should be worn , In case of high concentration, it is necessary to wear
air respirator or oxygen respirator.
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Eye
protection
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Normally
no need. If necessary, protective
chemical safety glasses should be worn.
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Body
protection
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Wear the
normal anti-static work clothes.
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Hand
protection
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Wear oil resistant rubber gloves
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Other protection
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No smoking, eating and drinking are allowed in working area. . Before
work to avoid drinking alcoholic beverages. After working, change clothes. It
is necessary to have physical examination before employment and the regular
physical examination .
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Appearance
and Character
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Primrose liquid
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Odour
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Characteristic smell
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PH
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Not available
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Flash point (Closed ℃)
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86
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Initial boiling point and
boiling range : (℃)
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140-230
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Freezing point (℃)
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C5H5Mn(CO)3
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Density（20℃）
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1.1+/-0.1g/cm3
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Not available
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Heat of combustion (kJ/mol)
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Not available
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Not available
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Octyl alcohol/water partition
coefficient of numerical
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Not available
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Solubility
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soluble in gasoline
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Lower Explosion limits%
(V/V)
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Upper
Explosion limits%(V/V)
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257
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Viscosity(25℃)
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1.7+/-0.2mpa
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Purpose
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Fuel additive, to improve
the gasoline
octane number and reduce
automobile
pollution.
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Other physicochemical property
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Not available
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Stability
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Stable
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Prohibited things
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Strong oxidizer
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Conditions
to avoid
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Keep
away from heat and direct sunlight.
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Polymerization harm
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Don't polymerization
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Decomposition
product
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Carbon monoxide, carbon
dioxide
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Acute poisoning
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LD50（rats，through the
mouth）9 to 176mg/kg；LC50（rats，Inhalation，4h）0.87mg/L。
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Chronic
poisoning
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The substance is
irritating to eyes and skin,which may act on the central nervous system,
kidney, liver and lung , influence of body, leading to tissue damage. When exposure to high concentrations, it
can lead to death. Need for medical observation.
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Subacute
and
chronic toxicity
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Not available
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Irritating
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Not available
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Allergenic
nature
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Not available
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Mutability
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Not available
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Not available
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Not available
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Ecological toxicology toxicity
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It is harmful to aquatic organism that may
cause long-term damage to the aquatic environment.
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Not available
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Non Biodegradability
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Not available
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Biological enrichment or
biological accumulating
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Not available
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Other deleterious effect
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Not available
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Waste properties
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Methods
of disposal
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To be treated by controlling
incineration
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Announcements of disposal
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Code of Dangerous Goods
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CN No.3281
Class 6.1
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UN code
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No.3281
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Packing mark
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Poison
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Wrapper Classes
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The United Nations packaging
categoryⅡ
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Packing method
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Special tank or iron drum
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Transport note
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In summer , it should be
shipped in the morning and evening to prevent sunlight exposure. Shipping
route should be according to the provisions of the route
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Regulatory
information
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In
Dangerous Chemicals Safety Management Regulations ( State Council Decree No.
344th ), the regulations have been
made for the chemical dangerous goods safety production, use, storage,
transportation, loading and unloading.
" Classification and Labels
of Dangerous Chemical " ( GB 13690-92 )
In ICSC " International
Chemical Safety Card " , the main
components are divided as follows :
6.1 The United Nations Risk
Categories: 6.1
China Risk categories: Article 6.1 Toxic
Substances
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References
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Department
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Safety
product department
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Company
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SNF PETROCHEM CO.,LTD.
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Date
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Nov.15, 2018
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Other information
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